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substances

Hydrogen cyanide

Poison and precursor

Hydrogen cyanide (HCN) is best known for its ability to cause death in a matter of minutes due to its toxicity. However, it also forms the basis of a much more important molecule: DNA. Could its presence point to the beginnings of life on other planets?

Javier Bardem as Raoul Silva in Skyfall

This ‘Substances’ will improve your knowledge of complex ions.

Hydrogen cyanide was first characterised by the Swedish chemist Carl Wilhelm Scheele in 1782. It was isolated from one of the first synthetic dyes, Prussian blue (see p. 34), which is featured in many famous paintings, particularly Hokusai’s The Great Wave off Kanagawa (see p. 12). It is also an important treatment for heavy metal and radiation poisoning, using its complex ion [Fe4[Fe(CN)6]3] through its tendency to exchange metal ions (Box 1).

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X-rays reveal a lost treasure

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